A simple local expression for the prefactor in transition state theory

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چکیده

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Variational Transition State Theory

Transition state theory (TST) 1 is the most widely used theory for calculating rates of bimolecular eactions occurring in the gas phase and in condensed phases. TST is also incorporated into the widely used RRKM theory for unimolecular reactions. The popularity of TST is largely due to its simplicity and its usefulness for correlating trends in reaction rates in terms of easily interpreted quan...

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ژورنال

عنوان ژورنال: The Journal of Chemical Physics

سال: 2019

ISSN: 0021-9606,1089-7690

DOI: 10.1063/1.5086746